Ferrocenecarboxaldehyde, cas is 12093-10-6, it is a common heterocyclic compound, the iron-catalyst compound, its synthesis route is as follows.
12093-10-6, General procedure: To a solution of [CpRu(PPh3)2Cl] (1 mol%) and solid aldehyde (1.0 mmol) in toluene (3 ml) was added PhSiH3 (1.2 mmol). The reaction mixture was stirred at reflux temperature under an air atmosphere (the reaction times are indicated in Table 4). Then, TBAF (1.0 mmol) was added and the reaction mixture was stirred at room temperature during 30 min. After evaporation, the reaction mixture was purified by silica gel column chromatography with ethyl acetate:n-hexane (1:3) to afford the corresponding alcohols.
With the rapid development of chemical substances, we look forward to future research findings about Ferrocenecarboxaldehyde
Reference£º
Article; Cabrita, Ivania R.; Florindo, Pedro R.; Fernandes, Ana C.; Tetrahedron; vol. 73; 11; (2017); p. 1511 – 1516;,
Iron Catalysis in Organic Synthesis | Chemical Reviews
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