Meso-5,10,15,20-Tetraphenyl-21H,23H-porphineironu-oxodimer, cas is 12582-61-5, it is a common heterocyclic compound, the iron-catalyst compound, its synthesis route is as follows.,12582-61-5
General procedure: To a CH2Cl2 solution (15 mL) of [(TPP)Fe]2(mu-O) (0.033 g, 0.024 mmol) was added trichloroacetic acid (0.010 g, 0.06 mmol). The mixture was stirred for 45 min, during which time the color of the solution changed from green to brown. The solvent was reduced to ?3 mL and hexane (10 mL) was added. The solution was slowly concentrated under reduced pressure until precipitation of the product occurred. The dark brown precipitate was collected by filtration, washed with hexane (2 ¡Á 15 mL), and dried in vacuo to give (TPP)Fe(OC(=O)CCl3) (0.020 g, 0.024 mmol, 50% isolated yield).
With the rapid development of chemical substances, we look forward to future research findings about Meso-5,10,15,20-Tetraphenyl-21H,23H-porphineironu-oxodimer
Reference£º
Article; Xu, Nan; Yan, Beiqi; Awasabisah, Dennis; Powell, Douglas R.; Richter-Addo, George B.; Inorganica Chimica Acta; vol. 469; (2018); p. 183 – 188;,
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