As a common heterocyclic compound, it belongs to iron-catalyst compound, name is Ferrocenecarboxaldehyde, and cas is 12093-10-6, its synthesis route is as follows.
General procedure: The ferrocenecarboxaldehyde (2.0mmol) and the acetyl pyridine or amino acetophenone derivatives (2.0mmol) were added to a round bottom flask at rt. Then, a freshly prepared NaOH solution (0.5mmol in 1.0 mL each of H2O and EtOH) was added dropwise and left stirring at rt. When completed, the resulting product was filtered at reduced pressure, washing with cold water. The crude product was then recrystallized as described. Compound 2a: 3-ferrocenyl-1-(2-pyridinyl) prop-2-en-1-one was obtained as dark violet crystals after recrystallization using acetone:H2O mixture. Yield: 0.41g (64%) of pure product. 1H NMR (500MHz, CDCl3): delta=8.73 (s, 1H), 8.18 (d, J=7Hz, 1H), 7.89 (s, 1H), 7.86 (d, J=4Hz, 2H), 7.46 (s, 1H), 4.67 (s, 2H), 4.49 (s, 2H), 4.18 (s, 5H). 13C NMR (125MHz, CDCl3): delta=188.5, 154.7, 148.8, 147.2, 137.0, 126.5, 122.9, 117.8, 79.5, 71.5, 69.9, 69.5. FT-IR (neat) numax (cm-1): 1659 (m), 1591 (m), 1574 (w), 1462 (w), 1396 (m).
12093-10-6, In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles.,12093-10-6 ,Ferrocenecarboxaldehyde, other downstream synthetic routes, hurry up and to see
Reference£º
Article; Delgado-Rivera, Sara M.; Perez-Ortiz, Giovanny E.; Molina-Villarino, Andres; Morales-Fontan, Fabiel; Garcia-Santos, Lyannis M.; Gonzalez-Albo, Alma M.; Guadalupe, Ana R.; Montes-Gonzalez, Ingrid; Inorganica Chimica Acta; vol. 468; (2017); p. 245 – 251;,
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