102-54-5, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. Ferrocene, cas is 102-54-5,the iron-catalyst compound, it is a common compound, a new synthetic route is introduced below.
To a three-neck flask, were added10.0 g of dry ferrocene (53.76 mmol) 150 mL of CH2Cl2. Then 39.2 g of triethylorthoformate (264.34) was added dropwise to the mixture with stirring. Afterthe ferrocene was completely dissolved, 30.0 g of mmol anhydrous AlCl3wasslowly added, and the reaction mixture was stirred at room temperature for4 h. Then the reaction was quenched with sodium hydrosulphite saturatedsolution (200 mL) and the mixture was extracted with diethyl ether (200 mL).After concentrated under reduced pressure, the residue was purified by chro-matography on silica gel (petroleum ether:ethyl acetate = 5:1) to afford 7 g redsolid with the yield of 70%.1H NMR (400 MHz, CDCl3) = 4.28 (s, 5H), 4.61 (s,2H); 4.80 (s, 2H), 9.96 (s, 1H).
Chemical properties determine the actual use. Each compound has specific chemical properties and uses. We look forward to more synthetic routes in the future to expand reaction routes of Ferrocene, 102-54-5
Reference£º
Article; I?ik, U?ur; Aydemir, Murat; Meric, Nermin; Durap, Feyyaz; Kayan, Cezmi; Temel, Hamdi; Baysal, Akin; Journal of Molecular Catalysis A: Chemical; vol. 379; (2013); p. 225 – 233;,
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