1271-51-8, Name is Vinylferrocene, belongs to iron-catalyst compound, is a common compound. 1271-51-8In an article, authors is Akiyama, Takeo, once mentioned the new application about 1271-51-8.
FORMATION OF ETHYNYL METALLOCENYL KETONE FROM 1,1,1-TRICHLORO-3-ALKOXY-3-METALLOCENYLPROPANE
1,1,1-Trichloro-3-ethoxy-3-ferrocenylpropane (1a) gives ethynyl ferrocenyl ketone (2a) via an unusual elimination of hydrogen chloride, when 1a is treated with alkali and then acid.The ruthenium analog (1b) also affords ethynyl ruthenocenyl ketone (2b).No migration of the side chain is involved in this process.
FORMATION OF ETHYNYL METALLOCENYL KETONE FROM 1,1,1-TRICHLORO-3-ALKOXY-3-METALLOCENYLPROPANE
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion