Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. 1293-65-8. Introducing a new discovery about 1293-65-8, Name is 1,1′-Dibromoferrocene
Synthesis of 1-[bis(trifluoromethyl)phosphine]-1′- oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates
A class of novel, easily accessible and air-stable 1-[bis(trifluoromethyl) phosphine]-1′-oxazolinylferrocene ligands has been synthesized from ferrocene. It became apparent that these ligands can be used in the regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates in a highly efficient manner. Excellent regio- and enantioselectivity could be obtained for a wide range of substrates.
Synthesis of 1-[bis(trifluoromethyl)phosphine]-1′- oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion