1271-51-8, Name is Vinylferrocene, belongs to iron-catalyst compound, is a common compound. 1271-51-8In an article, authors is Aukland, Miles H., once mentioned the new application about 1271-51-8.
An Interrupted Pummerer/Nickel-Catalysed Cross-Coupling Sequence
An interrupted Pummerer/nickel-catalysed cross-coupling strategy has been developed and used in the elaboration of styrenes. The operationally simple method can be carried out as a one-pot process, involves the direct formation of stable alkenyl sulfonium salt intermediates, utilises a commercially available sulfoxide, catalyst, and ligand, operates at ambient temperature, accommodates sp-, sp2-, and sp3-hybridised organozinc coupling partners, and delivers functionalised styrene products in high yields over two steps. An interrupted Pummerer/cyclisation approach has also been used to access carbo- and heterocyclic alkenyl sulfonium salts for cross-coupling.
An Interrupted Pummerer/Nickel-Catalysed Cross-Coupling Sequence
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion