Electric Literature of 1273-86-5, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 1273-86-5, Ferrocenemethanol, introducing its new discovery.
Regularities in formation of intramolecular hydrogen bonds with the metal atom Part I. alpha-Metallocenylcarbinols of the iron subgroup
Conditions for the formation of intramolecular hydrogen bonds in alpha-metallocenylcarbinols of the iron subgroup (M = Fe, Ru, Os) are determined.The combination of IR spectral data with conformational calculations has revealed situations where hydrogen bonding with the metal atom is determined by conformational preference.General rules govering the influence of the nature of the metal atom and the effect of substituents in the carbinol group and the cyclopentadienyl rings on the formation constants and relative stability of OH…Me intramolecular hydrogen bonds, on the proton-donating ability of the OH group and on the competition between intra- and intermolecular hydrogen bonds during self-association in the crystal, are estabished.
Regularities in formation of intramolecular hydrogen bonds with the metal atom Part I. alpha-Metallocenylcarbinols of the iron subgroup
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Electric Literature of 1273-86-5. In my other articles, you can also check out more blogs about 1273-86-5
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion