1273-86-5, Name is Ferrocenemethanol, belongs to iron-catalyst compound, is a common compound. name: FerrocenemethanolIn an article, once mentioned the new application about 1273-86-5.
Controlled Reduction of Carboxamides to Alcohols or Amines by Zinc Hydrides
New protocols for controlled reduction of carboxamides to either alcohols or amines were established using a combination of sodium hydride (NaH) and zinc halides (ZnX2). Use of a different halide on ZnX2 dictates the selectivity, wherein the NaH-ZnI2 system delivers alcohols and NaH-ZnCl2 gives amines. Extensive mechanistic studies by experimental and theoretical approaches imply that polymeric zinc hydride (ZnH2)? is responsible for alcohol formation, whereas dimeric zinc chloride hydride (H?Zn?Cl)2 is the key species for the production of amines.
Controlled Reduction of Carboxamides to Alcohols or Amines by Zinc Hydrides
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion