Reference of 1273-94-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1273-94-5, Name is 1,1′-Diacetylferrocene, molecular formula is C14H6FeO2. In a Article£¬once mentioned of 1273-94-5
Synthetic, structural and electrochemical studies on some ferrocenylazines: Crystal structures of [4](1)(1,4-dimethyl-2,3-diazabuta-1,3-dien) ferrocenophane and [42](1,1?)bist(1,4-dimethyl-2,3-diazabuta-1,3-dien) ferrocenophane
By reaction of the hydrazones of mono-and 1,1?-diacetylferrocene with mono-and diketones a series of ferrocenylazines has been prepared. The crystal structures of the monobridged ferrocenophane [4](1)(1,4-dimethyl-2,3-diazabuta-1,3-dien) ferrocenophane (II) and of the dibridged ferrocenophane [42](1,1?)bis-(1,4-dimethyl-2,3-diazabuta-1,3-dien) ferrocenophane (VII) have been determined. II exists as a centrosymmetric molecule with eclipsed cyclopentadienyl rings and a planar MeC=NN=CMe bridge whereas VII has staggered cyclopentadienyl rings and non-planar bridges. In II and VII the bridges are in the E,E configuration. The electrochemical results show that the ferrocenium ions of the acetylferrocene and the azines are stable in solution whereas those of the hydrazones are unstable. In agreement with a slightly increasing electronic communication between the two ferrocene units, II undergoes two almost overlapping one-electron oxidations (DeltaE? = 0.09 V) whereas VII displays two more widely separated one-electron oxidations (DeltaE? = 0.12 V).
Synthetic, structural and electrochemical studies on some ferrocenylazines: Crystal structures of [4](1)(1,4-dimethyl-2,3-diazabuta-1,3-dien) ferrocenophane and [42](1,1?)bist(1,4-dimethyl-2,3-diazabuta-1,3-dien) ferrocenophane
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 1273-94-5
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion