Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. Quality Control of Ferrocenemethanol. Introducing a new discovery about 1273-86-5, Name is Ferrocenemethanol
Catecholboryl-functionalized ferrocene based Lewis acid system: A selective probe for fluoride ion through multiple channels
The design and synthesis of two new receptors, C20H 19O3BFe and C20H21O3BFe and their anion sensing properties through multiple channels are reported. Both the receptors, having chelating boronic ester Lewis acidic centre as the sole binding site, selectively bind fluoride ion in micromolar concentration. The binding constant of C20H19O3BFe with the fluoride ion has been found to be quite high [K = 106 M -1], whereas it displays a negligible affinity towards other effective competitors, for example acetate and cyanide (K = 10 M-1) and no sensitivity towards other halide ions. Upon selective recognition of F- in acetonitrile, the redox potential of C20H 19O3BFe shifted by DeltaE = 200 mV and the fluorescence emission was quenched drastically. The considerable changes in their absorption spectra are accompanied by the appearance of a new low energy (LE) peak at 566 nm and by a strong colour change from yellow to deep green which allows the prospective for “naked eye” detection of F- anion.
Catecholboryl-functionalized ferrocene based Lewis acid system: A selective probe for fluoride ion through multiple channels
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Quality Control of Ferrocenemethanol, you can also check out more blogs about1273-86-5
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion