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Study of the inhibitive effect of mixed self-assembled monolayers on copper with SECM
Mixed self-assembled monolayers (SAMmix) were formed by 2-(Pyridin-2-yliminomethyl)-phenol (HL) and 1-dodecanethiol (DT) molecules on copper surface. The inhibitive ability of SAMmix in sodium chloride solution was characterized in situ by the scanning electrochemical microscope (SECM). The results show that the compactness and the stability of SAM mix, formed by the two organic materials in an appropriate sequence, are improved and the inhibition efficiency (eta%) increases markedly. They also verify that SAMmix are formed due to the existence of collapsed sites and pinhole defects on SAMs of single materials on the surface of copper. The re-arrangement and the competitive adsorption of HL and DT molecules may have impact on the quality of SAMmix. Possible structures of SAM mix are suggested based on the experimental results.
Study of the inhibitive effect of mixed self-assembled monolayers on copper with SECM
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Electric Literature of 1273-86-5. In my other articles, you can also check out more blogs about 1273-86-5
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Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion