Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. Computed Properties of C14H6FeO2. Introducing a new discovery about 1273-94-5, Name is 1,1′-Diacetylferrocene
Development of a convenient new synthetic route to [3]ferrocenophanones
[3]Ferrocenophanone rac-8 was prepared by several non-Friedel-Crafts pathways starting from a Mannich-type coupling of 1,1?-diacetylferrocene followed by catalytic hydrogenation. Hydride abstraction from the resulting alpha-dimethylamino[3]ferrocenophane rac-14 with B(C6F 5)3 followed by hydrolysis gave the ketone rac-8. Several variants of the Sommelet reaction, using ethylglyoxylate, formaldehyde or hexamethylenetetramine (urotropine) as the “oxidizing” reagent gave the alpha-[3]ferrocenophanone 8 in good to excellent yield. Some variants of these reactions were also used for the preparation of the pure enantiomer (R)-8. The electrochemical behaviour of 8 has been investigated and compared with related derivatives. The Royal Society of Chemistry 2006.
Development of a convenient new synthetic route to [3]ferrocenophanones
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Computed Properties of C14H6FeO2, you can also check out more blogs about1273-94-5
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion