In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Application In Synthesis of Ferrocenemethanol, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 1273-86-5, name is Ferrocenemethanol. In an article£¬Which mentioned a new discovery about 1273-86-5
Improved synthesis of diethyl ferrocenylphosphonate, crystal structure of (FcPOFcPO3Et22)2 ¡¤ZnCl 2, and electrochemistry of ferrocenylphosphonates, FcP(O)(OR)2, FcCH2P(O)(OR)2, 1,10?-fc[P(O)(OR)2]2 and [FcP(O)(OEt) 2]2 ¡¤ZnCl2
An improved synthesis of diethyl ferrocenylphosphonate using the tBuLi/tBuOK system at low temperature is reported and the structure of [FcPO3Et2]2 ¡¤ZnCl2complex is described. The electrochemical behaviour of FcP(O)(OEt)2, 1,1?-fc[P(O)(OEt) 2]2, FcCH2P(O)(OEt)2, and their corresponding acids were compared. Each of them shows a reversible one-electron transfer reaction. Ferrocenylbisphosphonate is more difficult to oxidize than ferrocenylphosphonate due to the presence of two electron-withdrawing substituents. A methylene spacer between the ferrocenyl unit and the phosphonate group renders the compound easier to oxidize. The acids are easier to oxidize than the esters, and their salts, in which the phosphonate group behave as an electron-donating group, are even easier to oxidize than the ferrocene. The ferrocenylphosphonic acid may be, then, considered as a redox-active pH responsive molecule. Elsevier B.V. All rights reserved.
Improved synthesis of diethyl ferrocenylphosphonate, crystal structure of (FcPOFcPO3Et22)2 ¡¤ZnCl 2, and electrochemistry of ferrocenylphosphonates, FcP(O)(OR)2, FcCH2P(O)(OR)2, 1,10?-fc[P(O)(OR)2]2 and [FcP(O)(OEt) 2]2 ¡¤ZnCl2
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 1273-86-5, help many people in the next few years.Application In Synthesis of Ferrocenemethanol
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion