1293-65-8, Name is 1,1′-Dibromoferrocene, belongs to iron-catalyst compound, is a common compound. name: 1,1′-DibromoferroceneIn an article, once mentioned the new application about 1293-65-8.
Synthesis, coordination chemistry, and catalytic application of a novel unsymmetrical P/O ferrocenediyl ligand
A novel, unsymmetrical 1,1?-disubstituted ferrocenediyl ligand, 1-(diphenylphosphino)-1?-(methoxy)ferrocene (3), featuring phosphine and ether substituents has been synthesized via two different routes and structurally characterized. Its coordination chemistry was investigated by reaction with Rh(I), Cu(I), and group 10 metal precursors. With Ni(II) precursors, chelating complexes are formed in high yield, whereas with Pd(II) and Pt(II) precursors, either chelating complexes or monodentate bis ligand complexes with trans phosphorus ligation may be formed depending on the reaction conditions and metal precursor employed. A similar monodentate trans phosphorus-ligated complex is observed with Rh(I), whereas with Cu(I) precursors, a phosphorus-ligated monodentate bis ligand complex with a coordinated acetonitrile was obtained. Preliminary studies show that 3, in combination with either Pd(II) or Pd(0) precursors, can act as a catalyst for the Suzuki coupling reaction.
Synthesis, coordination chemistry, and catalytic application of a novel unsymmetrical P/O ferrocenediyl ligand
Do you like my blog? If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 1293-65-8
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion