1271-51-8, Name is Vinylferrocene, belongs to iron-catalyst compound, is a common compound. Application In Synthesis of VinylferroceneIn an article, once mentioned the new application about 1271-51-8.
A chiral ferrocenesulfonic such P, P biligand synthetic method (by machine translation)
The invention discloses a chiral ferrocenesulfonic such P, P method for synthesizing of the ligand, belonging to the field of organic synthesis. This method is realized by the following steps : (1) with vinyl ferrocene as the starting material, chiral under the action of catalyst, and the two disclosed reaction to obtain (R) -1 the […] ferrocenesulfonic yl group II alkyl phosphine ; (2) (R) -1 the radicals […] ferrocenesulfonic yl acetate is disclosed and diethyl zinc reaction and the diphenyl phosphine reaction to obtain the chiral ferrocenyl such P, P ligand (R)-(-) – 1 the […] [(S) -2 the […] (mortars; concrete ; artificial stone) ferrocene] ethyl b is disclosed. Compared with the prior art, the present invention of fewer steps, the operation is simple, high yield, is more suitable for industrial production. Such chiral ferrocenyl made of P, P compounds can be used as the ligand of metal catalyst, used in the medical field. (by machine translation)
A chiral ferrocenesulfonic such P, P biligand synthetic method (by machine translation)
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion