Chemistry is traditionally divided into organic and inorganic chemistry. Safety of Ferrocenemethanol, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 1273-86-5
Nonbifunctional Outer-Sphere Strategy Achieved Highly Active alpha-Alkylation of Ketones with Alcohols by N-Heterocyclic Carbene Manganese (NHC-Mn)
The unusual nonbifunctional outer-sphere strategy was successfully utilized in developing an easily accessible N-heterocyclic carbene manganese (NHC-Mn) system for highly active alpha-alkylation of ketones with alcohols. This system was efficient for a wide range of ketones and alcohols under mild reaction conditions, and also for the green synthesis of quinoline derivatives. The direct outer-sphere mechanism and the high activity of the present system demonstrate the potential of nonbifunctional outer-sphere strategy in catalyst design for acceptorless dehydrogenative transformations.
Nonbifunctional Outer-Sphere Strategy Achieved Highly Active alpha-Alkylation of Ketones with Alcohols by N-Heterocyclic Carbene Manganese (NHC-Mn)
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion