Chemistry is traditionally divided into organic and inorganic chemistry. Application In Synthesis of Ferrocenemethanol, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 1273-86-5
Nucleophilic Addition of 1,1?-Bis(hydroxymethyl)ferrocene to Alkynes: Synthesis of Ferrocene Diethenyl Ethers
Chemoselective and atom-economical methods for the synthesis of ferrocene diethenyl ethers have been developed via direct base-catalyzed addition of 1,1?-bis(hydroxymethyl)ferrocene to various acetylenes. This ferrocene diol has been shown to be capable of adding to acetylene (KOH/DMSO, 70-80 C, 1-3 h), propyne (KOH/DMSO, 70 C, 12 h), phenylethyne (KOH/DMSO, 20-25 C, 48 h), alkylpropiolates (DABCO, 10 mol%/CH 2 Cl 2, 20-25 C, 0.5 h), and acylacetylenes (DABCO, 1 mol%/CH 2 Cl 2, 20-25 C, 0.5 h) to afford the corresponding diethenyl ethers in 73-98% yields.
Nucleophilic Addition of 1,1?-Bis(hydroxymethyl)ferrocene to Alkynes: Synthesis of Ferrocene Diethenyl Ethers
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion