In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 1273-94-5, name is 1,1′-Diacetylferrocene, introducing its new discovery. Recommanded Product: 1,1′-Diacetylferrocene
Homotrimetallic oxazolo-ferrocene complexes displaying tunable cooperative interactions between metal centers and redox-switchable character
A synthetic procedure based on the aza-Wittig reaction of alpha-azidoacetyl ferrocene or 1,1?-bis(alpha-azidoacetyl)ferrocene with mono-, di-, and triacyl chlorides and triphenylphosphine has been developed to prepare the new homotrimetallic ferrocene complexes 6, 9, and 10 containing at least two oxazole rings in the conjugation chain. Complexes 9 and 10 exhibited three and two reversible redox processes, respectively, indicating significant electrostatic interaction between the iron centers in these complexes. Protonation properties of complexes 9-13 have been assessed by use of 1H NMR and cyclic voltammetry measurements.
Homotrimetallic oxazolo-ferrocene complexes displaying tunable cooperative interactions between metal centers and redox-switchable character
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion