Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments. Safety of 1,1′-Ferrocenedicarboxaldehyde. Introducing a new discovery about 1271-48-3, Name is 1,1′-Ferrocenedicarboxaldehyde
Stepwise synthesis of octamethylferrocene-1,1?-dicarbaldehyde. Preparation of new electron donors for charge-transfer complexes
A stepwise synthesis of octamethylferrocene-1,1?-dicarbaldehyde (3), starting from 1,2,3,4-tetramethyl-5-(methoxycarbonyl)cyclopentadiene (7) is described, involving ferrocene formation, ester reduction to the corresponding bis(hydroxymethyl) derivative 9, and MnO2 oxidation. The aldehyde 3 readily reacts with different phosphonates derived from sulfurcontaining heterocycles in a Wittig-Horner reaction to form new electron donors that may be used in the preparation of various charge transfer complexes. The X-ray crystal structures of 1-[(1,3-benzodithiol-2-ylidene)methyl]-2,2?,3,3?,4,4?,5, 5?-octamethylferrocene (11a), 1-[(1,3-dithiolo[4,5-b][1,3]dithiol-2-ylidene)methyl]-2,2?,3,3?,4, 4?,5,5?-octamethylferrocene (11b), 1,1?-bis[(1,3-benzodithiol-2-ylidene)methyl]-2,2?,3,3?,4, 4?,5,5?-octamethylferrocene (12a), and 1,1?-bis[(5,6-dihydro-1,3-dithiolo[4,5-b][1,4]dithiol-2-ylidene)methyl]-2, 2?,3,3?,4,4?,5,5?-octamethylferrocene (12c) have been determined. In these compounds the planes of the sulfur heterocycles are oriented at angles of 60-75, with respect to the plane of the respective Cp ring.
Stepwise synthesis of octamethylferrocene-1,1?-dicarbaldehyde. Preparation of new electron donors for charge-transfer complexes
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Safety of 1,1′-Ferrocenedicarboxaldehyde, you can also check out more blogs about1271-48-3
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Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion