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Dinuclear platinum(II) complexes containing ferrocenylalkyl-thiolate and -selenolate ligands
Alkylation reactions of [Pt2(mu-S)2(PPh 3)4] with haloalkylferrocenes FcCH2Cl, Fc(CH2)6Br and Fc(CH2)11Br [Fc = (eta5-C5H5)Fe(eta5-C5H4)] gave the cationic mu-thiolate complexes [Pt2(mu-S){mu-S(CH2) nFc}(PPh3)4]+ (n = 1, 6, 11), isolated as PF6 and/or BPh4 salts, and characterised by ESI mass spectrometry, NMR spectroscopy, microelemental analysis, and by an X-ray structure determination on [Pt2(mu-S){mu-SCH2Fc} (PPh 3)4]PF6. The complex contains the typical folded {Pt2(mu-S)2} core with an axial ferrocenylmethylthi-olate ligand. The corresponding selenolate complex [Pt 2(mu-Se){mu-SeCH2Fc}(PPh3) 4]+ was similarly obtained by alkylation of [Pt 2(mu-Se)2(PPh3)4] with FcCH 2Cl, and isolated as PF6 and BPh4 salts. The attempted liberation of FcCH2SH from [Pt2(mu-S){mu- SCH2Fc}(PPh3)4]+ using Na 2S was not successful.
Dinuclear platinum(II) complexes containing ferrocenylalkyl-thiolate and -selenolate ligands
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion