Electric Literature of 1273-86-5, A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1273-86-5, Name is Ferrocenemethanol, molecular formula is C11H3FeO. In a Article£¬once mentioned of 1273-86-5
Dehydrogenation of alcohols by bis(phosphinite) benzene based and bis(phosphine) ruthenocene based iridium pincer complexes
Dehydrogenation of alcohols by three iridium pincer complexes, IrH(Cl)[2,6-(tBu2PO)2C6H 3] (1), {IrH(acetone)[2,6-(tBu2PO) 2C6H3]}{BF4} (2), and IrH(Cl)[{2,5-(tBu2PCH2)2C 5H2}Ru(C5H5)] (3), is reported, in both the presence and the absence of a sacrificial hydrogen acceptor. Dehydrogenation of secondary alcohols proceeds in a catalytic mode with turnover numbers up to 3420 (85% conversion) for acceptorless dehydrogenation of 1-phenylethanol. Primary alcohols are readily decarbonylated even at room temperature to give catalytically inactive 16e Ir-CO adducts. The mechanism of this transformation was studied in detail, especially for EtOH; new intermediates were isolated and characterized.
Dehydrogenation of alcohols by bis(phosphinite) benzene based and bis(phosphine) ruthenocene based iridium pincer complexes
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Electric Literature of 1273-86-5. In my other articles, you can also check out more blogs about 1273-86-5
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion