In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 1273-94-5, name is 1,1′-Diacetylferrocene, introducing its new discovery. category: iron-catalyst
Synthesis, structural characterization, and properties of a new range of strained 2-aza[3]ferrocenophane ligands: Dual behavior as electrochemical sensors of metal ions or anions
The synthesis of structurally new types of strained 2-aza[3]ferrocenophanes, 9 and 10, which comprise a benzoquinuclidine framework incorporating a 1,1?-disubstituted ferrocene unit is reported. These compounds were prepared in four steps from the readily available 1,1?-diacetylferrocene and thoroughly characterized by spectroscopic means and electrochemical methods. The ligands 9 and 10 act as electrochemical sensors either of Mg2-, Zn2-, and Ni2+ cations (free ligands), where a new redox peak appears in the CV shifted 310-350 mV, or hydrogensulfate anion (protonated ligand) via a significant cathodic perturbation. The crystal structures of compounds 9 and 9b (9¡¤HClO4) have been determined by single-crystal X-ray methods. In the latter compound the anion and cation are associated onto ribbons parallel to the z axis by four hydrogen bonds.
Synthesis, structural characterization, and properties of a new range of strained 2-aza[3]ferrocenophane ligands: Dual behavior as electrochemical sensors of metal ions or anions
We¡¯ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, the role of 1273-94-5, and how the biochemistry of the body works.category: iron-catalyst
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion