1273-86-5, Name is Ferrocenemethanol, belongs to iron-catalyst compound, is a common compound. Recommanded Product: FerrocenemethanolIn an article, once mentioned the new application about 1273-86-5.
A novel chiral phosphino-phosphaferrocene: Its coordination behavior and application to palladium-catalyzed asymmetric allylic alkylation
The synthesis of a novel chiral phosphino-phosphaferrocene ligand is described. The ligand possesses two electronically distinctive donor moieties and behaves either as a monodentate (with a free phosphaferrocene) or a bidentate ligand depending on stoichiometry with a coordinating transition-metal center. In the palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenyl-2-propenyl acetate, a clear correlation was observed between the enantioselectivity of the reaction and a Pd/phosphino-phosphaferrocene molar ratio. With a deficient amount (to the Pd) of the chiral ligand, the highest enantioselectivity (99% ee) was achieved.
A novel chiral phosphino-phosphaferrocene: Its coordination behavior and application to palladium-catalyzed asymmetric allylic alkylation
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion