Extended knowledge of 1,1′-Dibromoferrocene

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Simple Synthesis and Chemicophysical Properties of Polyoxaferrocenophanes and Its Alkali Metal Complexes

Polyoxaferrocenophanes were synthesized by a one-pot reaction of 1,1′-diacetoxyferrocene with dichloride.Crystalline 1 : 1 complexes of 3a with LiSCN, NaSCN, and KSCN were isolated.The 1H-NMR and Moessbauer spectra of these complexes suggest the possibility of a certain interaction between the iron atom of the ferrocene nuclei and complexed cation.The new type of ferrocenophane 3a extracts thallium ion most effectively, the extractability of several metal ions being in this order; Tl+ > Rb+ > K+ > Cs+ > Na+.

Simple Synthesis and Chemicophysical Properties of Polyoxaferrocenophanes and Its Alkali Metal Complexes

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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion