Related Products of 1271-48-3, Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction by binding to a specific portion of an enzyme and thus slowing or preventing a reaction from occurring. 1271-48-3, Name is 1,1′-Ferrocenedicarboxaldehyde, molecular weight is 242.0516. molecular formula is C12H10FeO2. In an Article£¬once mentioned of 1271-48-3
Preparation, characterization and electrochemical and X-ray structural studies of new conjugated 1,1?-ferrocenediyl-ended [CpFe-arylhydrazone] + salts
A series of new conjugated bimetallic ferrocenyl 1,1?-bis- substituted compounds of the type (E)-[CpFe(eta6-p-RC 6H4)NHN=CH(eta5-C5H 4)Fe(eta5-C5H4)-CH=CHC 6H4-p-R?]+PF6- (Cp = eta5-C5H5; R, R? = H, NO 2, 11; Me, NO2, 12; MeO, NO2, 13; Cl, NO 2, 14; Me, CN, 15; Me, Me, 16), with end-capped (E)-ethenylaryl and [CpFe(arylhydrazone)]+ substituents, have been prepared by the condensation reaction of 1,1?-(p-R?-arylethenyl) ferrocenecarboxaldehyde (R? = Me, 4; NO2, 5; CN, 6) with the organometallic hydrazine precursors [CpFe(eta6-p-RC 6H4NHNH2)]+PF6 – (R = H, 7; Me, 8; MeO, 9; Cl, 10). In the trimetallic series, {[CpFe(eta6-p-RC6H4)NHN=CH(eta 5-C5H4)]2Fe}2+[PF 6-]2 (R = H, 17; Me, 18; MeO, 19, Cl, 20), which results from the condensation of two equivalents of the same organometallic hydrazine precursor (7-10) with 1,1?- ferrocenedicarboxaldehyde, the ferrocenediyl core symmetrically links two cationic mixed-sandwich units. These ten hydrazones (11-20) were stereoselectively obtained as their trans isomers about the N=C double bond. All the new compounds were thoroughly characterized by a combination of elemental analysis, spectroscopic techniques (1H NMR, IR and UV-Vis) and electrochemical studies in order to prove electronic interaction between the donating and accepting units through the pi-conjugated system. A representative example of each series has also been characterized by single crystal X-ray diffraction analysis. The bimetallic complex 16+ adopts an anti conformation with the two iron atoms on opposite faces of the dinucleating hydrazonato ligand, whereas the trinuclear complex 192+ adopts a syn conformation with an Fe-Fe-Fe angle of 180. Other salient features of these structures are the long Fe-Cipso bond distances and the slight cyclohexadienyl character at the coordinated C6 ring, with a folding angle of 7.4 and 7.0 for 16+ and 19 2+, respectively.
Preparation, characterization and electrochemical and X-ray structural studies of new conjugated 1,1?-ferrocenediyl-ended [CpFe-arylhydrazone] + salts
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis. We will look forword to the important role of 1271-48-3, and how the biochemistry of the body works.Related Products of 1271-48-3
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion