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Ferrocenyl thioesters

Ferrocenyl thiols of the formula STR1 wherein n is an integer of from 2 to 4 are prepared by reacting a compoundf the formula STR2 with thioacetic acid, STR3 at elevated temperatures in the presence of a free radical initiator to produce a thiol ester of the formula STR4 and then hydrolyzing the thiol ester to produce the thiol. The thiols are useful as non-migrating burning rate modifiers for unsaturated rubber-based propellants.

Ferrocenyl thioesters

The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. name: Vinylferrocene, you can also check out more blogs about1271-51-8

Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion