Application of 1293-65-8, Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction by binding to a specific portion of an enzyme and thus slowing or preventing a reaction from occurring. 1293-65-8, Name is 1,1′-Dibromoferrocene, molecular weight is 335.76. molecular formula is C10Br2Fe. In an Article£¬once mentioned of 1293-65-8
Modular Synthesis of Fischer Biscarbene Complexes of Chromium
Aromatic and (hetero)aromatic chromium aminocarbenes were lithiated on the (hetero)aromatic ring and transmetalated with ZnBr2. The subsequent Pd(PPh3)4- or PdCl2(XantPhos)-catalyzed Negishi reaction with dibromoarenes or chromium alkoxy-/aminocarbenes bearing bromine atoms yielded bisaminocarbene or mixed bisalkoxyaminocarbene complexes of chromium. This methodology allows easy access to the biscarbene complexes containing poly(hetero)aromatic bridges, such as biphenylene, bithienylene, tetrathienylene, 1,1?-ferrocenylene, and others. In total, 18 new biscarbene complexes, including two containing both chromium and tungsten, were synthesized in this fashion. The electrochemical behavior of the biscarbenes obtained exhibits electronic communication between the metals.
Modular Synthesis of Fischer Biscarbene Complexes of Chromium
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms. In my other articles, you can also check out more blogs about 1293-65-8
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion