Reference of 1271-48-3, hemistry, like all the natural sciences, begins with the direct observation of nature¡ª in this case, of matter. In a document type is Article, molecular formula is C12H10FeO2, molecular weight is 242.0516, and a compound is mentioned, 1271-48-3, 1,1′-Ferrocenedicarboxaldehyde, introducing its new discovery.
Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly
Ferrocene-based Lewis bases have found utility as metalloligands in a wide variety of applications. The coordination chemistry of cyanoferrocenes however, is underexplored. Herein, we describe a new synthetic protocol for the generation of cyanoferrocenes. The coordination chemistry of these metalloligands to [Cu(NCMe)4][PF6], [(PPh3)2Cu(NCMe)2][PF6] and [(dppf)Cu(NCMe)2][PF6] salts has been explored, providing crystallographic evidence of cluster and polymeric forms of 1,1?- and 1,2-dicyanoferrocene complexes. The stability of the complexes and ligand dissociation were found to be strongly solvent-dependent.
Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly
In conclusion, we affirm that quantitative kinetic descriptions of catalytic behavior continue to serve as an indispensable tool.Reference of 1271-48-3. In my other articles, you can also check out more blogs about 1271-48-3
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion