Reference of 12180-80-2, Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction by binding to a specific portion of an enzyme and thus slowing or preventing a reaction from occurring. 12180-80-2, Name is 1,1′-Dibenzoylferrocene, molecular weight is 386.18. molecular formula is C24H10FeO2. In an Article£¬once mentioned of 12180-80-2
Studies on the cyclomercuration of 1,1?-bis[(arylimino)phenylmethyl]ferrocenes
The reaction of bisferrocenylimines with mercuric acetate and subsequent treatment with LiCl lead to formation of mono (9) and double (10) cyclomercurated derivatives. The 1H NMR and 199Hg NMR spectra of the double cyclomercurated bisferrocenylimines show that compounds 10 exist as two isomers (meso and dl). The individual stereoisomers were isolated successfully by crystal picking. The structures of these new compounds have been confirmed by elemental analysis, IR and 1H NMR spectroscopies, and further by X-ray crystal structure determination of meso [{HgCl(eta5-C5H3CPh=NAr)}2Fe] (Ar=m-CH3C6H4).
Studies on the cyclomercuration of 1,1?-bis[(arylimino)phenylmethyl]ferrocenes
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis. We will look forword to the important role of 12180-80-2, and how the biochemistry of the body works.Reference of 12180-80-2
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion