Extracurricular laboratory:new discovery of 1271-51-8

One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, COA of Formula: C12H3Fe, In homogeneous catalysis, catalysts are in the same phase as the reactants. In a article, mentioned the application of 1271-51-8, Name is Vinylferrocene, molecular formula is C12H3Fe

Unidirectional Current Flow and Charge State Trapping at Redox Polymer Interfaces on Bilayer Electrodes: Principles, Experimental Demonstration, and Theory

Bilayer electrodes consist of conductive electrodes coated with or bonded to two physically discrete polymeric layers which contain two different redox substances having different E0′ values.The redox substance in the inner polymeric film next to the electrode can be oxidized or reduced by the electrode.That in the outer polymer film is constrained, by physical isolation from the electrode, to undergo oxidation or reduction only at electron energies for redox conductivity by the inner film.This arrangement leads to rectified (unidirectional) current flow.Experimental results from bilayer electrodes based on nine different combinations of redox substances in the films are presented to demonstrate the generality of the phenomenon and the ability to fabricate bilayer film.The redox substances include fixed-site redox polymers like poly2+, polyvinylferrocene, poly(4-methyl-4′-vinyl-N,N’-ethylene-2,2′-bipyridinium), and siloxane polymer of N-methyl-N”-(4-(2-(trimethylsilyloxy)ethyl)benzyl)-4-4′-bipyridinium, and (inner film) mobile redox sites like bromide, hexachloroiridate, and benzophenone.Various mechanisms are considered for bilayer electrode nonidealities which appear as a leakage of redox state trapped in the outer film, an a theory describing voltammeric properties of bilayer electrodes is compared to experimental results.

Unidirectional Current Flow and Charge State Trapping at Redox Polymer Interfaces on Bilayer Electrodes: Principles, Experimental Demonstration, and Theory

The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis. We will look forword to the important role of 1271-51-8, and how the biochemistry of the body works.COA of Formula: C12H3Fe

Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion