Chemistry is a science major with cience and engineering. The main research directions are preparation and modification of special coatings, and research on the structure and performance of functional materials. In a patent, 1273-86-5, name is Ferrocenemethanol, introducing its new discovery. category: iron-catalyst
A cyclometalated iridium(III) complex containing a N?C?N-coordinating terdentate ligand [Ir(dpyx-N,C,N)Cl(mu-Cl)]2 was found to be a general and highly effective catalyst for the alpha-alkylation of ketones and N-alkylation of amines with alcohols. In the presence of catalyst (1 mol % Ir) and base (0.2-0.5 equiv), a variety of desirable products were obtained in good yields under an air atmosphere. Notably, this research exhibited the new potential of Ir(III) complexes bearing non-Cp? ligand and will facilitate the progress of the hydrogen autotransfer process.
Use of a Cyclometalated Iridium(III) Complex Containing a N?C?N-Coordinating Terdentate Ligand as a Catalyst for the alpha-Alkylation of Ketones and N-Alkylation of Amines with Alcohols
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. category: iron-catalyst, you can also check out more blogs about1273-86-5
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion