Synthetic Route of 1271-51-8, hemistry, like all the natural sciences, begins with the direct observation of nature— in this case, of matter. In a document type is Article, molecular formula is C12H3Fe, molecular weight is 203, and a compound is mentioned, 1271-51-8, Vinylferrocene, introducing its new discovery.
Acylferrocenes were synthesized by hydroiminoacylation of the omega-olefins 1-pentene (3a), vinylferrocene (3b) and but-3-enylferrocene (3c), with the ferrocenecarboxaldimine 2, prepared from ferrocenecarboxaldehyde (1) and 2-amino-3-picoline, under the action of Wilkinson’s catalysts, followed by hydrolysis of the corresponding ketimines (5a, 5b and 5c).This hydroiminoacylation was used to incorporate the ferrocenyl group into phenyl-terminated poly-butadiene (PTPB, consisting of 27percent vinyl and 73percent internal olefin group). 74percent hydroacylation of the vinyl group in 7 wasaccomplished in the first catalytic reaction and in 10 the second hydroacylation completed the conversion of the vinyl group into acylferrocene.
In conclusion, we affirm that quantitative kinetic descriptions of catalytic behavior continue to serve as an indispensable tool.Synthetic Route of 1271-51-8. In my other articles, you can also check out more blogs about 1271-51-8
Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion