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The synthesis and characterization of ferrocenylimidazole complexes of platinum(II) and palladium(II) are described. Reaction of ferrocenylimidazoles with K2MCl4 (M = Pd, Pt) using a biphasic system of dichloromethane and ethanol/water provided the corresponding complexes 2a-2j in good yields. New synthetic routes for the synthesis of ferrocenylbenzylethers 2k-2o, bis(4-ferrocenylbenzyl)carbonate [2p] and 4-ferrocenylbenzylacetate [2q] are also described. These products were obtained by the reaction of 4-ferrocenylbenzyl-1H-imidazole-carboxylate and K2PtCl4 under various conditions. Compounds 2k-2o were also obtained by alternative routes which do not involve the use of a platinum salt. The crystal structures of 2b, 2q and plausible mechanisms for the formation of 2k, 2p and 2q are reported.
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. Product Details of 1273-86-5, You can get involved in discussing the latest developments in this exciting area about 1273-86-5
Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion