Reference of 1273-86-5, With the volume and accessibility of scientific research increasing across the world, it has never been more important to continue building the reputation for quality and ethical publishing we’ve spent the past two centuries establishing.In an article, 1273-86-5, molcular formula is C11H3FeO, belongs to iron-catalyst compound, introducing its new discovery.
The tetrafluoborates of the primary, secondary, and tertiary ferrocenylmethyl carbenium ions have been prepared from the corresponding carbinols in ethyl ether, tetrahydrofuran and t-butyl methyl ether by adding HBF4.The NMR spectra of these salts, which dissolve in CDCl3, are characterized by the presence of very strong signals attributed to the ether used in the preparation, the solubility depending upon the structure of the cation and that of the ether.The NMR data suggest that alpha-ferrocenylcarbenium ions undergo two distinct types of solvation with ether-like donor molecules; one involves a much stronger interaction than the other.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion