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Electroactive ionic liquids obtained by modifying imidazolium with ferrocenyl moiety and alkyl chains of different lengths (n = 1, 4, 8 and 12) were studied in their pure form and dissolved in ethylene/diethylene carbonates (EC/DEC) solvent. Bis(trifluoromethanesulfonyl) imide (TFSI) was used as the anion. The conductivity of the pure ionic liquids (0.1 to 0.04 mS cm?1) was found to decrease with the increase in alkyl chain length as expected from larger van der Waals interactions. The conductivities of carbonate solutions of redox ionic liquid (50% vol.) were less affected by the chain length but were strongly dependent on the presence of Li ions due to their coordination with TFSI, providing viscous solutions (86-111 cP) which decreased the self-diffusion of the redox imidazolium by a factor of 6. The equilibrium potential of the RIL dissolved in the carbonate solvent was not affected by the alkyl chain length, but mass transport by migration caused a distortion in cyclic voltammograms for highly concentrated solutions.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion