Our Top Choice Compound: 1,1′-Dibromoferrocene

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Treatment of decaallylferrocene (1) with the Grubbs-II catalyst in refluxing dichloromethane has promoted the 5-fold ring-closing metathesis in 1 to afford single-bridged bis(1,4,5,8-tetrahydrofluorenyl)iron(II) species 3 in excellent yield. The preferential formation of 3 over quintuply bridged “superferrocenophane” 2 was explained as the intraannular RCM process being preferred over the interannular one in the reactions of polyallylferrocenes.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion