Formula: C11H3FeO, With the volume and accessibility of scientific research increasing across the world, it has never been more important to continue building the reputation for quality and ethical publishing we’ve spent the past two centuries establishing.In an article, 1273-86-5, molcular formula is C11H3FeO, belongs to iron-catalyst compound, introducing its new discovery.
The preparation and characterization of the three ferrocene based dithiolane complexes [(eta5-C5H5) Fe(eta5-C5H4)NHC(O)(CH2)4CHS 2CH2CH2]1, [(eta5- C5H5)Fe(eta5-C5H 4)CH2OC(O)(CH2)4CHS2CH 2CH2] 2 and [(eta5-C5H 5)Fe(eta5-C5H4)NHC(O)(CH 2)CHS2CH2CH2] 3, with different spacer groups between the ferrocenyl moiety and the dithiolane unit, are reported. The complexation of 1 and 2, using the oxidative addition of the S-S bonds to Pt(0), is also described, leading to the square planar Pt(II) complexes [Pt(PPh3)2(S2CH2CH 2CH-kappa2-S,S)(CH2)4C(O) NH(eta5-C5H4)Fe(eta5-C 5H5)] 4 and [Pt(PPh3)2(S 2CH2CH2CH-kappa2-S,S)(CH 2)4C(O)OCH2(eta5-C 5H4)Fe(eta5-C5H5)] 5, respectively. The reduction of the S-S bond in 1 and 2 yields the corresponding dithiols; these can be deprotonated and treated with ClSiMe3 to prepare [(eta5-C5H5)Fe(eta5- C5H4)NHC(O)(CH2)4CH(SSiMe 3)CH2CH2(SSiMe3)] 7 and [(eta5-C5H5)Fe(eta5-C 5H4)CH2OC(O)(CH2) 4CH(SSiMe3)CH2CH2(SSiMe 3)] 9, respectively. The complexes were characterized via NMR and UV-Vis absorption spectroscopy, cyclic voltammetry and single crystal X-ray diffraction for 1 and 4.
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. Formula: C11H3FeO, you can also check out more blogs about1273-86-5
Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion