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The synthesis and characterization of a novel class of highly-metallized, redox-active polyelectrolytes that employ phosphorus as a scaffold for the installation of transition metals is described. Pyrolysis of thin films of the title polyelectrolytes resulted in the production of magnetite crystallites and ill-defined carbon-, phosphorus- and oxygen-rich phases in char yields of nearly 50%. This journal is the Partner Organisations 2014.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion