Discover the magic of the Iron(II) acetate

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A reaction of nitrones with 1,2-dibromotetrafluoroethane affording bromodifluoroethyl-substituted hydroxylamines is described. The process is performed in the presence of a ruthenium photocatalyst and ascorbic acid as a stoichiometric reducing agent and is mediated by blue light irradiation. The fluroalkylation products can undergo chemoselective transformations involving either N?O or C?Br bonds furnishing various tetrafluorinated compounds. (Figure presented.).

The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. Recommanded Product: Iron(II) acetate, You can get involved in discussing the latest developments in this exciting area about 3094-87-9

Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion