You could be based in a university, combining chemical research with teaching; in a pharmaceutical company, working on developing and trialing new drugs; name: 1,1′-Dibromoferrocene, or in a public-sector research center, helping to ensure national healthcare provision keeps pace with new discoveries.In a article, mentioned the application of 1293-65-8, Name is 1,1′-Dibromoferrocene, molecular formula is C10Br2Fe
Two homologous ferrocene phosphanylcarboxylic acids, viz., 1?-[(diphenylphosphanyl)methyl]ferrocene-1-carboxylic acid (HL1) and [1?-(diphenylphosphanyl)ferrocenyl]acetic acid (HL2), were synthesized and studied as ligands in PdII complexes. The addition of these hybrid donors to [PdCl2(MeCN)2] led to the bis-phosphane complexes trans-[PdCl2(HL1-kappaP)2] and trans-[PdCl2(HL2-kappaP)2]. In contrast, the reactions of HL1 and HL2 with the PdII acetylacetonate (acac) complexes [(LYC)Pd(acac)], where LYC = 2-[(dimethylamino-kappaN)methyl]phenyl-kappaC1 (LNC) and 2-[(methylthio-kappaS)methyl]phenyl-kappaC1 (LSC), proceeded under proton transfer and replacement of the acac ligand, giving rise to O,P-bridged phosphanylcarboxylate dimers [LYCPd(mu(P,O)-L1)]2 and molecular chelates [LYCPd(L2-kappa2O,P)]2, respectively. The analogous reactions involving 1?-(diphenylphosphanyl)-1-ferrocenecarboxylic acid (Hdpf) provided the macrocyclic tetramer [LNCPd(mu(P,O)-dpf)]4 and the dimer [LSCPd(mu(P,O)-dpf)]2. The reactions of HL1 with [Pd(acac)2] only led to an ill-defined, insoluble material, whereas those with HL2 produced a separable mixture of the bis-chelate complexes trans-[Pd(L2-kappa2O,P)2], cis-[Pd(L2-kappa2O,P)2], and [Pd(acac)(L2-kappa2O,P)].
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis. We will look forword to the important role of 1293-65-8, and how the biochemistry of the body works.name: 1,1′-Dibromoferrocene
Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion