SDS of cas: 1273-86-5, Chemistry graduates have much scope to use their knowledge in a range of research sectors, including roles within chemical engineering, chemical and related industries, healthcare and more. 1273-86-5, Name is Ferrocenemethanol, molecular weight is 206.99. In an Article，once mentioned of 1273-86-5
A kinetic study of the one electron oxidation of substituted ferrocenes (FcX: X = H, COPh, COMe, CO2Et, CONH2, CH2OH, Et, and Me2) by a series of N-oxyl radicals (succinimide-N-oxyl radical (SINO), maleimide-N-oxyl radical (MINO), 3-quinazolin-4-one-N-oxyl radical (QONO) and 3-benzotriazin-4-one-N-oxyl radical (BONO)), has been carried out in CH3CN. N-oxyl radicals were produced by hydrogen abstraction from the corresponding N-hydroxy derivatives by the cumyloxyl radical. With all systems, the rate constants exhibited a satisfactory fit to the Marcus equation allowing us to determine self-exchange reorganization energy values (lambdaNO/NO-) which have been compared with those previously determined for the PINO/PINO- and BTNO/BTNO- couples. Even small modification of the structure of the N-oxyl radicals lead to significant variation of the lambdaNO/NO- values. The lambdaNO/NO- values increase in the order BONO < BTNO < QONO < PINO < SINO < MINO which do not parallel the order of the oxidation potentials. The higher lambdaNO/NO- values found for the MINO and SINO radicals might be in accordance with a lower degree of spin delocalization in the radicals MINO and SINO and charge delocalization in the anions MINO- and SINO- due to the absence of an aromatic ring in their structure. This is the end of this tutorial post, and I hope it has helped your research about 1273-86-5, you can contact me at any time and look forward to more communication. SDS of cas: 1273-86-5
Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion