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Four organometallic nucleobases have been prepared and characterized, each consisting of a disubstituted ferrocene unit connected through either a conjugated or saturated linker group to adenine or thymine nucleobases. Their assembly behavior has been studied in the solid state via X-ray crystallography, revealing intermolecular H-bonded arrays. The electrode potentials in DCM are strongly dependent upon the nature of the linker group between the ferrocene unit and the nucleobase.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion