SDS of cas: 12180-80-2, Academic researchers, R&D teams, teachers, students, policy makers and the media all rely on us to share knowledge that is reliable, accurate and cutting-edge. In a document type is Article, and a compound is mentioned, 12180-80-2, name is 1,1′-Dibenzoylferrocene, introducing its new discovery.
In the solid state, molecules of 1,1?-dibenzoylferrocene, [Fe(Cl12H9O)2], (I), are linked to form infinite chains in the [100] direction via (cyclopentadienyl)C – H…O hydrogen bonds [C…O 3.354 (4) A]. In the structure of (4-nitrophenyl)ferrocene, [Fe(C5H5)(C11H8NO2)], (II), there are no C – H-…O hydrogen bonds and molecules are separated by normal van der Waals distances. For earlier determinations see Struchkov [Dokl. Akad. Nauk SSSR (1956), 110, 67-70] for (I) and Roberts et al. [J. Chem. Soc. Dalton Trans. (1988), pp. 1549-1556] for (II).
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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion