With the volume and accessibility of scientific research increasing across the world, it has never been more important to continue building the reputation for quality and ethical publishing we’ve spent the past two centuries establishing.In an article, 1273-86-5, molcular formula is C11H3FeO, belongs to iron-catalyst compound, introducing its new discovery., Application of 1273-86-5
Palladium-catalyzed coupling reactions of 6,6?-dihydroxyboron-2, 2?-dimethoxy-1,1?-binaphthyl 5g and chloroarenetricarbonylchromium complexes 6a – c afforded complexes 7a – c with the binaphthyl residue directly linked to the (eta6-arene)tricarbonylcriromium entity. Coupling reactions of 2,2?-dimethoxy, 3,3?diodo, and 6,6?-diodo-1, 1?-binaphthyl 3h and 5h with ethynylarenetricarbonylchromium derivatives 6d – f and ethynylferrocene 9 yielded binaphthyl compounds linked to arenetricarbonylchromium and feirocenyl derivatives 8a – c, 11a – c, 10, and 12 through a triple bond. Condensation of 2,2?-dimethylrriethoxy, 3-formyl, 1,1?-binaphthyl 2a with (eta6-phenyl) methyltriphenylphosphonium tricarbonylchromium 13 and ferrocenylmethyltriphenylphosphonium 18 gave binaphthyl compounds linked to arenetricarbonylchromium and ferrocenyl derivatives 14 and 19, respectively, through a double bond. X-ray analyses of the dinuclear chromium complex 8a and of the mononuclear chromium complex 17-Z are described.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion