Application In Synthesis of Ferrocenemethanol, With the volume and accessibility of scientific research increasing across the world, it has never been more important to continue building the reputation for quality and ethical publishing we’ve spent the past two centuries establishing.In an article, 1273-86-5, molcular formula is C11H3FeO, belongs to iron-catalyst compound, introducing its new discovery.
The homogeneous electrocatalytic mechanism with a fast catalytic chemical reaction between a series of ferrocene derivatives and L-cysteine/N-Acetyl-L-cysteine (NAC) is systematically investigated. A comparison of different cyclic voltammetric waveforms is given to illustrate the interaction between kinetic parameter (lambda) and excess factor (gamma) in kinetic zone diagram via changing the scan rates and substrate/mediator ratio on both glassy carbon (GC) and boron doped diamond (BDD) working electrode experimentally. A split wave phenomenon is observed between ferroceneacetic acid (FAA) and L-cysteine. Also, the waveforms revealed that electron withdrawing groups (EWG) on the substrate hinders the kinetics of the homogeneous electron transfer while those on the mediator facilitates the same process. The homogeneous electrocatalytic order of the studied mediator is as follows: 1,1?-ferrocenedicarboxylic acid (FDA) > FAA > hydroxymethylferrocene (HMF) > 1-hydroxyethylferrocene (HEF) and the corresponding density functional theory (DFT) calculation is applied to support this statement. Furthermore, the second-order rate constant between FAA and L-cysteine is given by the support of numerical simulation (175 (mol m?3)?1 s?1). The present study would facilitate the understanding of homogeneous electrocatalytic process, especially those possessing a fast catalytic chemical step.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion