You could be based in a university, combining chemical research with teaching; in a pharmaceutical company, working on developing and trialing new drugs; category: iron-catalyst, or in a public-sector research center, helping to ensure national healthcare provision keeps pace with new discoveries.In a article, mentioned the application of 1271-48-3, Name is 1,1′-Ferrocenedicarboxaldehyde, molecular formula is C12H10FeO2
The chiral 1,1?-bis-acetals, bis-1,1?-[(2S, 4S)-(hydroxymethyl)-2-dioxane1,3]-ferrocene (3) and 1,1?-bis-1,1?-[(2S, 4S)-(methoxymethyl)-2-dioxane1,3]-ferrocene (4) were synthesized. (3) was crystallographically characterised. The ortholithiation of (4) was studied in various conditions. Fair yields of monosubstituted compounds could be obtained with a complete regioselectivity in favor of the 2 position but the diastereoselectivities were moderate (up to 35%). Some disubstituted compounds can be isolated but in low yields (up to 8%). The regioselectivity is complete in favor of the 2,2?-disubstituted isomer. Only the diastereoisomer with two opposite planar chiralities is observed.
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. category: iron-catalyst, You can get involved in discussing the latest developments in this exciting area about 1271-48-3
Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion