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A one-pot, four-component, copper-catalysed double-“click” functionalisation of a novel 1,1?-desymmetrised ferrocene backbone is reported. Using an array of alkynes and azides, a library of ferrocene compounds was developed, demonstrating the scope of this methodology for its potential application in the assembly of novel materials, ligands or biological sensors.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion