You could be based in a university, combining chemical research with teaching; in a pharmaceutical company, working on developing and trialing new drugs; Recommanded Product: 1,1′-Ferrocenedicarboxaldehyde, or in a public-sector research center, helping to ensure national healthcare provision keeps pace with new discoveries.In a article, mentioned the application of 1271-48-3, Name is 1,1′-Ferrocenedicarboxaldehyde, molecular formula is C12H10FeO2
The first organometallic derivatives of tricyclic quinazoline derivatives are prepared by condensation of the active C-3 methylene group of 7H-deoxyvasicinones with ferrocenecarbaldehyde. By following this route the conjugated parent alkaloid and derivatives with nitro, amino, as well as some alkanoylamino groups at C-7 were attached at the ferrocene moiety, thereby significantly extending the pi system. In addition, the parent compound was subjected to the reaction by treatment with ferrocene-1,1?-dicarbaldehyde, giving rise to the double condensation product, which is only the second case of a 1,1?-disubstituted ferrocene derivative with two alkaloid substituents. A number of the compounds obtained were subjected to X-ray crystallographic analyses. In all cases, the substituents adopt a coplanar conformation with the ferrocene cyclopentadienyl ligands. The influence of the substituents at C-7 through the extended conjugated pi system on the iron atom is reflected by results of cyclic voltammetric measurements as well as by DFT calculations. 7H-Deoxyvasicinones are condensed with ferrocenecarbaldehyde and with ferrocene-1,1?-dicarbaldehyde to generate extended pi systems with coplanar conformations of the two moieties. The products are investigated by crystal structure analyses, cyclic voltammetry, and DFT calculations.
The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. Recommanded Product: 1,1′-Ferrocenedicarboxaldehyde, You can get involved in discussing the latest developments in this exciting area about 1271-48-3
Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion