08/9/2021 News Can You Really Do Chemisty Experiments About 1273-86-5

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Chemical engineers ensure the efficiency and safety of chemical processes, adapt the chemical make-up of products to meet environmental or economic needs, and apply new technologies to improve existing processes. Related Products of 1273-86-5. Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. Introducing a new discovery about 1273-86-5, Name is Ferrocenemethanol

Treatment of ferrocenecarboxaldehyde with base at 0 deg C, lithium diisopropylamide (LDA) or n-butyllithium, followed by the addition of trimethylsilylcyanide, produced 1-(diisopropylamino)cyanomethylferrocene, FcCH(N2)(CN) (II) or 1-trimethylsiloxy-n-pentylferrocene.FcCH(nBu)OSiMe3 (IIIa).The reaction of naphthaldehyde, NpCHO, with LDA/Me3SiCN led to formation of 1-(diisopropylamino)cyanomethylnaphthalene, NpCH(CN) suggesting a general new synthesis for cyanoamines.The reaction of ferrocenecarboxaldehyde with Me3SiCN led to the expected silylether FeCH(CN)OSiMe3 (I).An alternative synthesis of ferrocenylmethylsilylethers, FeCH2OSiR3 (IV), involved the reaction of 1-ferrocenylmethanol with R3SiCl in the presence of pyridine.The basicity of the new silylethers III and IV is reported.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion